Well, I'd chip in with 'Licence to Kill', which is actually a pretty solid spy thriller, spoiled only by the need to have signature Bond paraphernalia like gadgets, and babes, and villains with sharks.

Meanwhile, from a parallel universe, don't forget the incredible performance that Irvin Kershner got out of Sean Connery's hairpiece in 'Never Say Never Again'.

Most importantly, if you can answer the question of why James Bond, Jason Bourne and Jack Bauer all have the same initials, I'd be the least bit surprised.

Any reason why this doesn't appear in the list of episodes on iTunes?

I searched for 'The Blob' on the iTunes Store, and it helpfully suggested: "Did you mean 'The Bob'?" Which, to give them their due, does have a lot more wrong search results.