All great suggestions guys.
A little more clarity on what I'm doing. I'm currently an executive producer with the horror audio YouTube channel Chilling Tales for Dark Nights. We produce high quality adaptations of horror stories (with author permission) and give them a cinematic sound.
We caught the attention of PodcastOne, one of the biggest podcasting networks around. They optioned a podcast version of what we're doing on YouTube, which will include a host who will introduce the stories, banter, interview guests etc.
My role will be as producer, as in post-producer. All the recording of the host will be handled by the host himself, who is a voiceover professional and runs his own home studio. He'll be sending me his completed audio every week and my job will be to edit the episode by placing his dialogue in front, in between and after stories. I'll also be handling some background music responsibilities and creating the website for the show.
So this isn't quite your typical podcast in the sense that it's all done in post, really. Nonetheless, I'm still curious about podcasting best practices and any tips I can glean, so I appreciate the feedback!